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orapwd

orapwd file=password_file_name password=the_secret_password
orapwd file=password_file_name password=the_secret_password entries=n
There is a default location and name for password files. When a password file is created, it should be created in that location.
n specifies the maximum number of distinct DBAs and OPERs that can be stored in the password file.
orapwd is a command line tool to create password files.